lablichtenberg.bsky.social
Research in main group chemistry with a focus on bismuth compounds for synthesis, catalysis, and materials science. Radical species, cationic compounds, unconventional structural motifs.
👤 Joined on 26 April 2025
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@lablichtenberg.bsky.socialSTRONTIUM POWER: Although this series follows the octet rule, only neutral Ph3N is stable. Ph3B is very resistant to double reduction. Only Ar3B.- radical anions are known. However, it had to surrender to strontium. doi.org/10.1002/anie...
Show PostSOLVENT-FREE ALKALINE-EARTH ALKYLS are very useful precursors in group 2 chemistry. Here we report facile syntheses of highly reactive Ca, Sr and Ba complexes, partially by ball-mill methods. doi.org/10.1021/acs....
Show PostGroup alumnus Dr Jingjing Liu and I have written a review on lanthanide and actinide bulky silylamide chemistry in Coordination Chemistry Reviews. I hope the community finds this to be a useful resource for designing low-coordinate f-block complexes: www.sciencedirect.com/science/arti...
Show PostAnother nice collab with @marcuswdrover.bsky.social on hydrostibination chemistry! This time revealing the H-Al-Sb functional group! chemrxiv.org/doi/full/10....
Show PostBeautiful vanadium complexes and their interconversion within! You can read the full paper for free, here: doi.org/10.1039/d6sc...
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