Kana M Sureshan
kana-m-sureshan.bsky.social
Professor at IISER Thiruvananthapuram, India. Research interests: Supramolecular chemistry, Organic chemistry, Peptides, Gels, Topochemical reactions, Crystal engineering https://kms514.wixsite.com/kmsgroup/publications
👤 Joined on 30 March 2026
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- 30 Mar 2026, 14:50
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Can one solid-state reaction create conditions for the next? Our work, “Sequential Topochemical Reactions Through an Evolving Reaction Lattice,” is just in Angew. Chem. We uncover a two-stage topochemical cascade in a xerogel: MONOMER → DIMER → POLYMER doi.org/10.1002/anie...
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📢 Hiring a postdoc! Join my group on an NIH-funded project developing hydrazone-based photoswitchable fluorophores for super-resolution microscopy. Looking for expertise in organic synthesis, photochemistry, spectroscopy, systems/supramolecular chemistry, and/or chemical biology. #chemjobs #chemsky
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Here, we show that the stability of imines in water can be significantly enhanced by adding a flanking coordination bond. As a result, imines form with a near-quantitative yield when aldehyde and amine are mixed in a stoichiometric ratio in water buffered at pH 7.
Show PostImine bonds are a cornerstone of supramolecular chemistry because they combine the strength of a covalent bond with the reversibility on a non-covalent bond. However, the quantitative formation of imine bonds in water has proven challenging due to their low stability in this solvent.
Show PostNew paper published on the near-quantitative formation of imines in water ! with Tommaso Marchetti Lorenzo Goldin @benjaminoacid.bsky.social @deepaky25.bsky.social Federico Rastrelli and Luca Gabrielli pubs.acs.org/doi/10.1021/... #ChemSky
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